Hello Sunnybay and welcome to the forum. I keep looking at your problem and try to think why your car should start when the engine is hot but not when the outside ambient air temperature is hot.
It may be worth investigating the fuel lines and in particular the breather/vent pipe.
http://www.detali.ru/cat/oem_mb2.asp...SGR=045&SGN=03 http://www.detali.ru/cat/oem_mb2.asp...SGR=060&SGN=04
Have you tried undoing the filler cap and releasing any pressure before trying to start the car?